Kings of Leon will star in a special MTV World Stage production the night before the 2016 MTV EMAs.
The concert will take place at the Old Luxor Theater in Rotterdam, the Netherlands, on Saturday, November 5.
The band have previously given World Stage performances in Hamburg and Dublin. Their seventh studio album WALLS went straight in at No.1 in the UK Official Albums Chart last week.
They will also perform at the 2016 MTV EMAs, which will broadcast live from the Ahoy Rotterdam on Sunday, November 6 at 8pm.
Hosted by Bebe Rehxa, the event will also feature acts including Bruno Mars, OneRepublic, Martin Garrix, Afrojack, Shawn Mendes, DNCE, Lukas Graham and Zara Larsson.