The move will see EMI chairman Guy Hands step back to become non-executive chairman of the major.
During Leoni-Sceti's 16-year career with Reckitt Benckiser he has been responsible for what EMI calls "some outstanding brand successes", as well as strengthening "its recognised leadership in product innovation and global branding".
Reckitt Benckiser brands include Airwick, Veet, Calgon and Cillit Bang.
Hands says, "I am delighted that Elio is joining as chief executive of EMI Music to lead the most exciting business ...
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