The event, now in its 12th year, will take place on May 12 at the Royal Albert Hall.
It will be hosted by Myleene Klass for a fourth consecutive year, while performers include the cast of Les Miserables with Alfie Boe as Jean Valjean.
Russell Watson and Katherine Jenkins will perform with Il Divo making their Classic Brits debut.
The London Chamber Orchestra conducted by Christopher Warren Green will accompany all performers.
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