The double set is presently a few thousand sales ahead of its nearest rival, fellow Warner Bros release The Resistance by Muse, which debuted at one last Sunday.
If Celebration remains in front it will place Madonna in joint second place with Presley behind The Beatles with the most UK chart-topping albums. Her tally of 10 album number ones dates back to 1984's Like A Virgin and also takes in the Evita soundtrack, which features both her and other artists.
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