The former Velvet Underground singer and the heavy metal titans will be performing together on Later... to promote their new collaborative album Lulu, set for release on October 31.
Reed has already called the unlikely collaboration the "best thing I ever did" and UK viewers will have the opportunity to see for themselves when they grace the Later... studio.
Other guests in series 39 include Coldplay, Red Hot Chili Peppers, Laura Marling, Bjork, Little Dragon, Tony Bennett, Peter Gabriel, Florence ...
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